Thin Film, Foil, Metal Oxide, Thick Film and Carbon Resistors

23 Sep.,2024

 

Thin Film, Foil, Metal Oxide, Thick Film and Carbon Resistors

Apart of wirewound resistors resistive elements may be produced and arranged in a lot of different ways by non-wirewound technologies.

You will get efficient and thoughtful service from Xieyuan Electronic.

We shall present in the article the following resistor types, differentiated by constructional material or specific design such as thin film, foil, thick film and carbon resistors.

Metal film / thin film
Metal foil
Metal glaze/ thick film
Metal oxide /&#;metox&#;
Carbon film, Carbon composition and Conductive plastic

Table 1. Technologies for low power fixed resistors &#; TCR vs Tolerance

Introduction to Film Resistors

Film resistors are built either on cylindrical rods or on planar substrates. Usually the material in the rods and substrates is ceramic in the state of aluminum oxide (alumina), but glass may occur. Hollow cores exist but are more and more abandoned when sizes are becoming smaller. This design suffers also from drawbacks: the construction is more fragile and the heat dissipation is poorer than that of a solid core.

Through-hole mount

A typical film resistor is shown in Figure 1.

Figure 1. Cutaway view of film resistor.Figure 2. Schematic of a spiraled film resistor.

The film of the cylindrical rods thus are cut in a helical track to a long path, usually with a laser. A more stylized sketch is shown in Figure 2. The pitch of the helix track can be varied in order to increase the resistance of the film. For thick films an increase of up to 150 times, for carbon and metal films up to times or even more.

As indicated in the figure a stray capacitance is developed between the turns. Because the turns also constitute a coil the resistor will get a certain inductance. All in all the spiraling produces a frequency dependent impedance where the capacitance is dominating. The conditions are illustrated by the Figure 3.

Film resistors may be approximately classified as follows:

  • values < 100Ω are inductive.
  • values between 100Ω and 470Ω are practically true resistive.
  • values above 470Ω  are capacitive.
Figure 3. Equivalent circuit for film resistors.

Fusible and flameproof resistors

A strong overload of carbon and metal film resistors will lead rapidly to an open circuit that in most cases is accompanied by a build-up of smoke, glow or even fire. Some manufacturers have developed designs that burn off within certain limits. They are called fusible resistors. The open-circuit conditions are defined in particular power-time diagrams. The limits still must be regarded as &#;broad&#;.

If coatings and casings are used that don&#;t generate or sustain a fire, we talk about flameproof resistors. The drawback with these casings in past was partly an impaired environmental protection and partly a troublesome environmental disadvantage from a recycling viewpoint, since they often contain bromine compounds. The modern flameproof resistors has replaced the bromine based fire retardants by a metal oxide compounds. Check with manufacturer datasheets.

Chips and Networks

Film resistors also exist as discrete SMD chips or in so called resistor networks where they are collected under a common housing.

Load Chart Nomogram

The connection between stability, operating time, temperature, power and resistance usually are shown in particular nomographic load charts. Figure 4. shows such a diagram for a sample film resistor. The example reveals how an 1 kΩ resistor working with 0.24 W at an ambient temperature of 80 °C gets a Hot Spot temperature of approximately 137 °C which after 10 000 hours operation produces an expected resistance change of approximately 0.4%. Such a modest change indicates a considerable derating of the nominal power that very well could have been 0.4 or 0.5 W in this example.

Consequently a nomographic load diagram corresponds only to one type and size (power).

In the nomograph example below you shall start at the actual power on the load axes and draw a horizontal line to the right to the parameter of actual ambient temperature. From that point of intersection you draw a perpendicular line that crosses the axis for actual Hot Spot temperature, and continue to the parameter of actual resistance. There you continue horizontally to the parameter of estimated time of operation. From this point of intersection you then continue 90° upwards to the axes marked with the corresponding calculated resistance change.

Figure 4. Nomographic load diagram for a fictitious film resistor.

Metal Film / Thin Film Resistors

Today the most dominant type of resistor is the metal film. Sometimes it is called thin film. From the beginning precious metals or resistive alloys were evaporated in a vacuum process and evaporated on ceramic rods. But the TCR specifications especially were hard to fulfil (TCR = temperature coefficient of resistance). Stability and TCR accuracy took a leap forward when one passed to metal ion bombardment of the rods (so called sputtering). Today all the techniques have been developed and refined.

The evaporation technique works both with a vacuum process and a chemical volatility process. Sput­tering and ion implanting have become synonymous concepts. The technical progress today motivates manufacturing of high precision resistors. We talk about the third generation of metal/thin film resistors.

Common film alloys are nichrome (CrNi) or tantalum nitride (Ta2N), often with additives of aluminum (Al), silicon (Si) or titanium (Ti). The tantalum nitride has very fine low noise characteristics and is superior in hi-fi applications. Generally, metal film resistors keep noise down by means of laser spiraling that properly utilized produces even tracks free from irregularities.

Occurrence of non-linearity &#; distortion &#; is mastered by measurement of the third harmonic distortion and automatic screening, where failing parts not meeting stated requirements are removed from the lot.

Distinctive of the metal films is their thin layers &#; 50&#; Å or,  0.005&#;0.5 μm (0.2 &#;20 microinches). The thinnest films correspond to the highest resistance values where the film starts approaching molecular thicknesses and to some extent deviates from the noise-free conduction capability of metals. Thus the noise is increasingly greater in the high resistance range. Films thinner than 350 Å should be avoided in noise sensitive designs. Another reason for avoiding them is their extreme sensitivity to moisture related electrolytic corrosion, especially if the film consists of a chromium-nickel alloys. Since the film thickness is not stated in the data sheets we may obtain a certain guidance of where the film is getting too thin for high-reliability applications by dividing the manufactured maximum value by 10. Then choose from several serious manufactures the highest manufactured value of the size in question. If the maximum value is, for example, 15 MΩ this rule of thumb gives an upper limit value of 1.5 MΩ. If the application is a dry room environment without large temperature variations (no risk of condensation) and low noise requirements we may use considerably higher resistive values. But still we should, both for reliability and above all availability reasons, take care not to use the highest manufactured maximum value.

Check with other serious manufacturers where their maximum values are and purchase a little bit below the lowest maximum value.

Also, the relatively thickest films are thin and corrosion disposed in moisture, especially if they are working with DC loads. A good encapsulation therefore is necessary. US MIL components exist with hermetic seals but they are relatively expensive. Epoxy/plast­ic molding does not always offer the same good protection as lacquered coverings, at least not if the lacquer is applied in several thin layers. Farthest in there are one or several &#; often transparent &#; coatings of lacquer followed by several layers of colored lacquer. Here the Europeans are far ahead. Duplicated production of cheap standard components with multilayer lacquered coverings probably will come rather close to optimum with regard to price and quality.

Another risk zone for metal film resistors is the ESD &#; electrostatic discharge. The closer the tolerances, the more important is part protection against ESD.

Finally, metal film resistors are sensitive to power pulses. The power will warm up the thin resistance track very rapidly. Consequently also short pulses may lead to a risk of burning-off or too high temperatures that may hazard the stability. Conservative recommendations talk of maximum 2 x PR where PR stands for rated power. At all events we should not exceed 4 x PR even if the mean power is within specified limits. Single pulses may be much higher but we have to inquire into every particular case: type, manufacturer, value, environment&#;

Low Ohmic Designs

Values below 10 ohms previously have been manufactured  so that the ceramic rods are plated with a resistive alloy, in a bath or a burning process, or by electroplating. The plated layer then will become proportionately thick &#; between 1 and 5 μm (0.04 and 0.2 mils) &#; and will have a very good pulse power capability. But tolerances and TC values will be poorer. In the lowest resistance values there is no spiraling which will improve the pulse capability further.

Today some manufacturers have succeeded in producing low ohmic resistors down to 0.1 ohm with the sputtering technique. This eliminates the plating technique difficulties with TCR and tolerance but impairs the pulse capability.

Power and Precision Types

If we load a conventionally power rated metal film resistor with a higher power the temperature will raise and this in turn will decrease stability. Thus power resistors in metal film often have the tolerance ±5% in the E24 series. Alloys and lacquers have been chosen in order to endure higher operation temperatures.

If we go in the other direction and reduce the power &#; derate &#; and, moreover, lower the maximum permissible ambient temperature, we get a very stable resistor. IEC 115-5 divides in that way the same sizes in different stability classes, from 0.5 to 0.05 %. It&#;s the same philosophy as behind precision wirewound resistors. High stability resistors can be worth producing in fine tolerances and TC values. Thus precision resistors of the market are characterized by a low power rating, fine tolerances, low TCR values and a high stability. Note, however, that TC information sometimes is connected to restrictions in the temperature range. The finer the TC, the more narrow the temperature range.

In order to increase the stability further, high precision components are subjected to aging processes where one already under the manufacture releases prospective changes.

Linear PTC designs

If we choose metal film alloys that bring out the positive TC of the metals &#; positive temperature coefficient, PTC &#; we get relatively linear PTC resistors. Values between + and + ppm/°C are offered. Just as for the wirewound counterparts the resistance range is limited upwards.

Mounting

At least 0.5 mm air space or additional insulation should separate the resistors from adjacent metal parts, for example conductive patterns on printed circuit boards.

Metal Foil Resistors

Within the metal film technology there is a particular type of precision resistor made by metal foils, by the inventor, Vishay, called Bulk metal foil. These resistors exist both in axial and radial designs for hole mount, further as SMDs, networks and power styles, finally also in PTC designs.

Figure 5. Cutaway view of (bulk) metal foil resistor.; source: VPG foil resistors

Figure 5. shows a principle cutaway view of a foil resistor from the manufacturer VPG foil resistors. The etching pattern is not shown.

For more glass glaze resistorinformation, please contact us. We will provide professional answers.

The coefficients of the thermal expansion of the resistance alloy and substrate are different. When the alloy foil is firmly attached to the ceramic substrate in a unique way it results in a compressive stress on the alloy when temperature increases. The resistivity of the alloy versus temperature changes is matched with variations of the resistance of the alloy with stress. In other words, by this method the physical expansion behavior of the foil is forced to follow the considerably lower expansion or shrinkage movements of the substrate at temperature changes. This results in a foil with excellent stability and TCR characteristics. The construction also results in outstanding characteristics of thermal electromotive forces and voltage coefficients.

The foil then is etched to a serpentine or labyrinth pattern, either by means of a photo resistive film, mask and chemical etching (photo lithography), or by means of a guided ion beam. Particular, not mold encapsulated styles, can be bought together with trimming tools. By scribing an open-circuit in particular conductance paths the resistance value may be trimmed to extremely fine tolerances. The patterns eliminate much of the inductance that burdens spiraled components.

Since the foils have thicknesses of more than 2.5 μm (0.1 mil) they have excellent pulse resistant characteristics. They don&#;t suffer from the extreme corrosion sensitivity of thin films either. The disadvantage is that the maximum resistance of metal foil styles will be limited (See Table R3-1).

The most common failure mode of metal foil resistors is open-circuit in contact joints after temperature changes or of shifts in resistance as debris or weak spots in the resistive path burn out.

Table 2. METAL FILM  &  METAL FOIL RESISTORS CHARACTERISTICS

Metal Glaze / Thick Film Resistors

If we screen print a paste of finely scattered metal particles (for example ruthenium, ruthenium oxide, rhodium, palladium, tantalum-tin) together with glass powder on a ceramic substrate and fire the film until the glass melts, we get a resistive film from some μm up to 25 μm (1 mil) of thickness, a so called thick film or metal glaze. The substrate has to be chosen with great care in order to constitute an integrated part of the melted glass powder. A variant of thick film exists in some potentiometers under the name of cermet. Actually it is a manufacture connected film that first was put on the market by the manufacturer Beckman Industrial. Today the name cermet is generally recognized.

Figure 6. metal glaze thick film resistor construction; source: Viking Tech

The film is very environment resistant and has surface resistivities up to 1 MΩ/square, which allows high resistance values in small chip sizes. Here the thick film meets with its dominating application together with its existence in networks. Axial through hole mounted components are manufactured almost exclusively as high ohmic/high voltage types. Traditional high ohmic resistors in the 100-MΩ range of carbon composition, carbon film or metal oxide designs generally with advantage can be replaced with metal glaze resistors.

After the firing cylindrical bodys are spiraled as shown in Figure 1. and 2. Plane surfaces are laser trimmed to exact values. The tolerances usually are situated between 1 and 10 % and the TCRs between ±25 and ±300 ppm/°C. The closest TCR, ±25 ppm, deserves certain caution because of the risk of drift outside the specification limits.

The conduction mechanism in the metal glaze/ thick film consists of contacts between small metal granules. This leads to considerably more noise than in genuine metal film resistors. Furthermore the user should be careful with strong pulse loads, at least in the k range. They might give permanent resistance changes due to damaged contact points.

Another phenomenon that characterizes thick film materials more than pure metals is non-linearity. The thick film with its complicated conduction network and countless contact spots suffers from non-linearity at relatively low resistance values. Following diagrams show the difference between thick film and metal film materials in two SMD styles: a metal film &#;MELF&#; and a thick film chip.

Figure 7. Examples of third harmonic attenuation in different resistor materials.Table 3. METAL GLAZE / THICK FILM RESISTORS CHARACTERISTICS

Metal Oxide (&#;METOX&#;)

The metal oxide resistors have increasingly been replaced by metal film resistors. But, they still have a market, above all in the high ohmic-high voltage range. Precision designs exist in all resistance ranges.

There are different ways of producing resistive metal oxide films. If we heat ceramic rods in a vapor of stannic chloride we get a coating of stannic oxide with good resistive characteristics. The thickness is approximately 1μm (0.04 mils). If we instead use glass that in a hot state is extruded in a stannic chloride vapor, it will result in a film of stannic oxide that is integrated with the glass to form an environment resistive resistance film. It will withstand several hundred per cent overload with good stability. On the other hand these resistors are extremely sensitive to stronger power pulses, also of short duration. Another way to produce metal oxide films is to first apply a metal film on the rods and then oxidize the film in an oxygen gas.

Figure 8. Inductance limiting serpentine pattern burnt on a cylindrical rod of metal oxide &#;METOX&#; resistors. Caddock Electronics, Inc.Figure 9. metal oxide METOX resistor construction

Normally the rods are spiraled in a conventional way. The lead pattern, however, can be formed in an inductance-limiting serpentine pattern as shown in Figure 8. and 9.

The metal oxide film has excellent noise characteristics, next to metal films the best. Unlike other films it does not run the risk of being oxidized at higher temperatures.

It already is oxidized. Thus, in certain power resistors Hot Spot temperatures up to 275 °C are permitted. But the user needs to check with the manufacturer&#;s data sheet about how much the chosen type can stand. It varies. Sometimes the power types are supplied with cooling plates integrated with the housing.

Certain types of metal oxide films also are suited for high voltage or high ohmic types, the latter in values up to at least 100 GΩ.

Table 4. METAL OXIDE (&#;Metox&#;) RESISTORS CHARACTERISTICS

Carbon Film and Carbon Composition Resistors

Carbon Film Resistors

Carbon film resistors sometimes are called surface layer resistors. Better qualities are classified as &#;stable&#; with a ΔR/R that will stop at &#;1%. Their role has, to a great extent, been taken over by the metal film but they still have a market, especially as cheap 5 per cent E 24 components. At new designs one should yet consider replacing them with metal film resistors that also are offered in E 24, 5 per cent. See Figures 10. and 11.

Figure 10. Carbon film resistors constructionFigure 11. Carbon film resistors

If we apply crystalline carbon on ceramic rods in a vacuum chamber or if we heat them up to temperatures close to °C and then let them be hit by hydrocarbons, carbon will be deposited at a cracking process which will produce a stable, resistive carbon film with TCR values between &#;250 and &#; ppm/°C depending on the resistance value. The thickness typically varies between 0.04 and 40 μm (1.6 and microinches). Low resistance values and corresponding thick films give an excellent pulse capability that may be further amplified if the film is non-spiraled.

Somewhere below 10Ω the manufacturers pass from carbon film to metal films (nickel, chromium-nickel or nickel-phosphorous) that is applied in a chemical bath or burning process or in an electrolytic bath. Thus, the user should carefully note in the catalogue sheets at which resistance value the TCR alters from, for example,  &#;250 to maybe ±200 ppm/ °C.

The stability of carbon film resistors is good. The noise is comparatively high and increases with the resistance; low values may be relatively noise free, equivalent to that of the metal oxide.

High ohmic types exist in their most exclusive form in a hermetically sealed state, usually glass tubes, and may reach TΩ values (x ). Don&#;t touch such components with your fingers. Perspiring hands might be enough for shunting down the rated resistance markedly.

Table 5. CARBON FILM RESISTORS CHARACTERISTICS

Carbon Composition Resistors

This component type is on the point of disappearing from the market. The manufacture of certain designs has ceased. In the most cases carbon composition resistors can be replaced by other both cheaper and qualitatively better components. Nevertheless, since they are part of many older designs we therefore will discuss them.

Carbon composition resistors exist in several designs: homogeneous and heterogeneous. In the first case a compound consisting of carbon powder and binder together with a resin is molded to a resistive body. In the latter case the carbon powder is mixed with a filling, usually silica or aluminum oxide, before it is molded. This type has the poorest stability and parameter characteristics. In a third variant a dispersion of graphite and binder is applied on a glass tube and then dried. The parameter characteristics of that layer type are comparable with those of the homogeneous composition type but the construction is very vulnerable.

The homogeneous, molded type is qualitatively the best but also the most expensive. It is usually used in such applications where an open circuit failure mode would result in a serious safety risk. In Figure 9. a cutaway view is shown of homogeneous composition resistor.

Figure 9. Cutaway view of homogeneous carbon composition resistorFigure 10. Principle sketch of the resistance element in an homogeneous carbon composition resistor.

Just as in metal glaze resistors the conduction mechanism consists of conductive granules embedded in an isolator compound (Figure 10.). There is shown the capacitive connection between the separate carbon granules. This will lead to a strong capacitive shunting effect at higher frequencies. Some curves are shown in Figure 11.

Figure 11. Impedance versus frequency in a ½W carbon composition resistor.

If the capacitive frequency dependence is great the inductance is the smaller. The current passes through an infinite number of branches connected in parallel which altogether creates a negligible inductance inside the resistor body. This, however, doesn&#;t mean that we have found the ideal component for pulse loads even if we occasionally may see such assertions. Only low resistance values, where the resistor body consists mainly of pure carbon, may correspond to such assertions. Otherwise strong surge currents might damage the uncountable contact spots in the current paths. The pulse power Pp should be limited to

carbon composition pulse power equation [1]

Caution! Parts from less serious manufactures may have a fire risk at improper overload conditions.

The temperature dependence is strongly non-linear. Table 6.

Current noise and stability are poor. The method to adjust low or decreasing resistance values by baking gives only temporary results. After some time the value is too low again. As said before, there are few reasons for choosing a carbon composition resistor.

Table 6. CARBON COMPOSITION RESISTORS CHARACTERISTICS

Conductive Plastic Resistors

Of the fundamentally important resistance materials only one remains to be mentioned: the conductive plastic. It is closely related to the carbon composition. Actually it belongs to the potentiometers but for consistency reasons is presented in this article.

If carbon powder and thermosetting plastic together with a binder are mixed together and molded we get a so called conductive plastic. It is used above all in servo potentiometers due to its low friction and excellent wear resistance. The resistance stability is fairly good provided it is not subjected to too high relative humidity or condensation.

Table 7.  CONDUCTIVE  PLASTIC RESISTORS CHARACTERISTICS

If you want to learn more, please visit our website metal oxide film resistor.